Evaluation of salt weathering in stone using a new test procedure: a comparative laboratory study


Published: Jun 17, 2024
Keywords:
Salt crystallization Natural stone Micro-destructive tests RILEM
Loucas Kyriakou
Ioannis Ioannou
Magdalini Theodoridou
Derrick Mwebaza
Abstract

Exposure to natural weathering and deleterious agents poses a significant risk to traditional porous building materials, like stone and mortar, with salt crystallization featuring as a prominent degradation mechanism. Despite the existence of standardized laboratory tests to assess the salt crystallization resistance of stone, the international scientific community still seeks more reliable and reproducible alternatives. In this framework, RILEM TC ASC-271 recently recommended a novel accelerated test procedure for assessing the resistance of natural stone and fired-clay brick units against salt crystallization. This study assesses RILEM’s recommendation by comparing results from laboratories in Cyprus and the UK on a particular lithotype. The interlaboratory results show similar mass losses, with higher values reported with an increase in the salt concentration used. Micro-destructive cutting tests adopted to locate the salt crystallization front at the end of the procedure revealed layers of increased resistance behind the evaporation surface of the test specimens because of pore clogging. The reproducibility of the results reported and the efficiency of the micro-destructive cutting techniques employed in mapping the salt front suggest that the new test recommendation may be used effectively in the lab to predict damage due to salt crystallization in natural stone.

Article Details
  • Section
  • Part IV - Methodologies for Characterization and Damage Assessment
Author Biographies
Loucas Kyriakou

Department of Civil and Environmental Engineering, University of Cyprus, Nicosia, Cyprus

Ioannis Ioannou

Department of Civil and Environmental Engineering, University of Cyprus, Nicosia, Cyprus

Magdalini Theodoridou

School of Engineering, Hub for Biotechnology in the Built Environment, Newcastle University, Newcastle upon Tyne, United Kingdom

Derrick Mwebaza

School of Engineering, Hub for Biotechnology in the Built Environment, Newcastle University, Newcastle upon Tyne, United Kingdom

References
Charola A. E.: Salts in the deterioration of porous materials: an overview,” J. Am. Inst. Conserv. 39(3), 327-343 (2000). DOI: 10.1179/019713600806113176
Doehne E.: Salt weathering: a selective review. Geol. Soc. Spec. Publ. 205, 51-64 (2002). DOI: 10.1144/GSL.SP.2002.205.01.05
Graue B., Siegesmund S., Oyhantcabal P., Naumann R., Licha T., Simon K.: The effect of air pollution on stone decay: the decay of the Drachenfels trachyte in industrial, urban, and rural environments – a case study of the Cologne, Altenberg and Xanten cathedrals. Environ. Earth Sci. 69, 1095-1124 (2013). DOI: 10.1007/s12665-012-2161-6
Benavente D., De Jongh M., Cañaveras J.C.: Weathering Processes and Mechanisms Caused by Capillary Waters and Pigeon Droppings on Porous Limestones. Minerals 18, 1-16 (2021). DOI: 10.3390/min11010018
Ioannou I., Hoff W.D.: Water repellent influence on salt crystallisation in masonry. Proc. Inst. Civ. Eng.: Constr. Mater. 161, 17-23 (2008). DOI: 10.1680/coma.2008.161.1.17
Espinosa-Marzal R. M., Scherer G. W.: Crystallization of sodium sulfate salts in limestone. Environ. Geol. 56, 605-621 (2008). DOI: 10.1007/s00254-008-1441-7
Espinosa R. M., Franke L., Deckelmann G.: Model for the mechanical stress due to the salt crystallization in porous media. Constr. Build. Mater. 22, 1350-1367 (2008). DOI: 10.1016/j.conbuildmat.2007.04.013
Lubelli B., Rörig-Dalgaard I., Aguilar A. M., Aškrabic M., Beck K., Bläuer C., Cnudde V., D’Altri A. M., Derluyn H., Desarnaud J., Diaz Gonçalves T., Flatt R., Franzoni E., Godts S., Gulotta D., van Hees R., Ioannou I., Kamat A., De Kock T., Menendez B., de Miranda S., Nunes C., Sassoni E., Shahidzadeh N., Siedel H., Slížková Z., Stefanidou M., Theodoridou M., Veiga R., Verge`s-Belmin V.: Recommendation of RILEM TC 271-ASC: New accelerated test procedure for the assessment of resistance of natural stone and fired-clay brick units against salt crystallization. Mat. Struct. 56, 101 (2023). DOI: 10.1617/s11527-023-02158-0
Modestou S., Theodoridou M., Fournari R., Ioannou I.: Physico-mechanical properties and durability per-formance of natural building and decorative carbonate stones from Cyprus. Geol. Soc. Spec. Publ. 416, 145-162 (2016). DOI: 10.1144/SP416.3
Theodoridou M., Dagrain F., Ioannou I.: Micro-destructive cutting techniques for the characterization of natural limestone. Int. J. Rock. Mech. Min. Sci. 76, 98-103 (2015). DOI:10.1016/j.ijrmms.2015.02.012
Theodoridou M., Török Á.: In situ investigation of stone heritage sites for conservation purposes: a case study of the Székesfehérvár Ruin Garden in Hungary. Prog. Earth Planet Sci. 6, 15 (2019). DOI: 10.1186/s40645-019-0268-z
Kyriakou L., Theodoridou M., Ioannou I.: Micro-destructive evaluation of the mechanical properties of lime-based mortars. J. Cult. Herit. 58, 219-228 (2022). DOI: 10.1016/j.culher.2022.10.007
Kyriakou L., Theodoridou M., Ioannou I.: Standardised experimental techniques and novel micro-destructive methods for the assessment of lime mortar properties. In: RILEM Proceedings PRO 128 of SMSS 2019 Sustainable Materials, Systems and Structures – Novel Methods for Characterization of Mate-rials and Structures, Rovinj, Croatia (2019).
Kyriakou L., Theodoridou M., Ioannou I.: Micro-destructive evaluation of lime mortar compressive strength using the scratching and drilling resistance tools. International RILEM LHS Workshop – Lime based materials for repairing historic structures, Thessaloniki, Greece (2022).
Kyriakou L., Sanchez A. M. A., Nunes C., Ioannou I.: Assessment of salt distribution in Maastricht and Migné limestones with the use of micro-destructive techniques. Proceedings of SWBSS 2021 – Salt weathering of buildings and stone sculptures, 153-162 (2021).
Nunes C., Sanchez A. M. A., Godts S., Gulotta D., Ioannou I., Lubelli B., Menendez B., Shahidzadeh N., Slížková S., Theodoridou M.: Towards a more effective and reliable salt crystallization test for porous building materials – Part I: Experimental research on salt contamination procedures and methods for as-sessment of the salt distribution. Constr. Build. Mater. 298, 123862 (2021). DOI: 10.1617/s11527-018-1180-5
Modestou S., Theodoridou M., Ioannou I.: Micro-destructive mapping of the salt crystallization front in limestone. Eng. Geol. 193, 337-347 (2015). DOI: 10.1016/j.enggeo.2015.05.008
Detournay E., Defourny P.: A phenomenological model for the drilling action of drag bits. Int. J. Rock Mech. Min. Sci. Geomech. Abstr. 29, 13-23 (1992). DOI: 10.1016/0148-9062(92)91041-3