The 3-Dimensional g-Deformed Harmonic Oscillator and a Unified Description of Magic Numbers of Metal Clusters


N. Karoussos
Dennis Bonatsos
P. P. Raychev
R. P. Roussev
Abstract

Magic numbers predicted by a 3-dimensional (/-deformed harmonic oscillator with u9(3) D soq(3) symmetry are compared to experimental data for atomic clusters of alkali metals (Li, Na, K, Rb, Cs), noble metals (Cu, Ag, Au), divalent metals (Zn, Cd), and trivalent metals (Al, In), as well as to theoretical predictions of jellium models, Woods-Saxon and wine bottle potentials, and to the classification scheme using the 3n + / pseudo quantum number. In alkali metal clusters and noble metal clusters the 3-dimensional çr-deformed harmonic oscillator correctly predicts all experimentally observed magic numbers up to 1500 (which is the expected limit of validity for theories based on the filling of electronic shells), while in addition it gives satisfactory results for the magic numbers of clusters of divalent metals and trivalent metals, thus indicating that ug(3), which is a nonlinear extension of the u(3) symmetry of the spherical (3-dimensional isotropic) harmonic oscillator, is a good candidate for being the symmetry of systems of several metal clusters.

Article Details
  • Section
  • Oral contributions (deprecated)
References
W. A. de Heer, Rev. Mod. Phys. 65 (1993) 611.
M. Brack, Rev. Mod. Phys. 65 (1993) 677.
V. O. Nesterenko, Fiz. Elem. Chastits At. Yadra 23 (1992) 1665 [Sov. J. Part. Nucl. 23 (1992) 726.
W. A. de Heer, W. D. Knight, M. Y. Chou and M. L. Cohen, Solid State Phys. 40 (1987) 93.
M. G. Mayer and J. H. D. Jensen, Elementary Theory of Nuclear Shell Structure (Wiley, New York, 1955).
T. P. Martin, T. Bergmann, H. Göhlich and T. lange, Chem. Phys. Lett. 172 (1990) 209; Ζ. Phys. D 19 (1991) 25.
S. Bj0rnholm, J. Borggreen, 0. Echt, K. Hansen, J. Pedersen and H. D. Rasmussen, Phys. Rev. Lett. 65 (1990) 1627; Ζ. Phys. D 19 (1991) 47.
W. D. Knight, Κ. Clemenger, W. A. de Heer, W. A. Saunders, M. Y. Chou and M. L. Cohen, Phys. Rev. Lett. 52 (1984) 2141.
J. Pedersen, S. Bj0rnholm, J. Borggreen, K. Hansen, T. P. Martin and H. D. Rasmussen, Nature 353 (1991) 733.
C. Bréchignac, Ph. Cahuzac, M. de Frutos, J.-Ph. Roux and K. Bowen, in Physics and Chemistry of Finite Systems: From Clusters to Crystals, edited by P. Jena et al. (Kluwer, Dordrecht, 1992), Vol. 1. p. 369.
C. Bréchignac, Ph. Cahuzac, F. Carlier, M. de Frutos and J. Ph. Roux, Phys. Rev. Β 47 (1993) 2271.
W. D. Knight, W. A. de Heer, Κ. Clemenger and W. A. Saunders, Solid State Commun. 53 (1985) 445.
Ν. D. Bhaskar, R. P. Frueholz, C. M. Klimcak and R. A. Cook, Phys. Rev. Β 36 (1987) 4418.
Η. Göhlich, T. Lange, T. Bergmann and T. P. Martin. Phys. Rev. Lett. 65 (1990) 748.
T. Bergmann, H. Limberger and T. P. Martin, Phys. Rev. Lett. 60 (1988) 1767.
I. Katakuse, T. Ichihara, Y. Fujita, T. Matsuo, T. Sakurai and H. Matsuda, Int. J. Mass Spectrom. Ion Processes 67 (1985) 229.
M. B. Knickelbein, Chem. Phys. Lett. 192 (1992) 129.
G. Alameddin, J. Hunter, D. Cameron and M. M. Kappes, Chem. Phys. Lett. 192 (1992) 122.
I. Katakuse, T. Ichihara, Y. Fujita, T. Matsuo, T. Sakurai and H. Matsuda, Int. J. Mass Spectrom. Ion Processes 69 (1986) 109.
J. L. Persson, R. L. Whetten, H. P. Cheng and R. S. Berry, Chem. Phys. Lett. 186 (1991) 215.
Κ. Clemenger, Phys. Rev. Β 32 (1985) 1359.
S. G. Nilsson, Mat. Fys. Medd. Dan Vid. Selsk. 29, no 16 (1955).
S. G. Nilsson and I. Ragnarsson, Shapes and Shells in Nuclear Structure (Cambridge University Press, Cambridge, 1995).
W. Ekardt, Ber. Bunsenges. Phys. Chem. 88 (1984) 289; Phys. Rev. Β 29 (1984) 1558.
D. E. Beck. Solid State Commun. 49 (1984) 381; Phys. Rev. Β 30 (1984) 6935.
Β. Α. Kotsos and M. E. Grypeos, in Atomic and Nuclear Clusters, edited by G. S. Anagnostatos and W. von Oertzen (Springer, Berlin, 1995), p. 242.
L. C. Biedenharn, J. Phys. A 22 (1989) L873.
A. J. Macfarlane. J. Phys. A 22 (1989) 4581.
V. Chari and A. Pressley, A Guide to Quantum Groups (Cambridge University Press, Cambridge, 1994).
A. Klimyk and K. Schmiidgen, Quantum Groups and Their Representations (Springer, Berlin, 1997).
D. Bonatsos, C. Daskaloyannis, P. Kolokotronis and D. Lenis, Rom. J. Phys. 41 (1996) 109.
D. Bonatsos, C. Daskaloyannis and K. Kokkotas, J. Math. Phys. 33 (1992) 2958.
P. P. Raychev, R. P. Roussev, N. Lo Iudice and P. A. Terziev, J. Phys. G 24 (1998) 1931.
Yu. F. Smirnov, V. N. Tolstoy and Yu. I. Kharitonov, Yad. Fiz. 54 (1991) 721
[Sov. J. Nucl. Phys. 54 (1991) 437];
Yu. F. Smirnov and Yu. I. Kharitonov, Yad. Fiz. 56 (1993) 263;
Phys. At. Nucl. 56 (1993) 1143;
Yad. Fiz. 59 (1996) 379 ;
Phys. At. Nucl. 59 (1996) 360;
A. A. Malashin, Yu. F. Smirnov and Yu. I. Kharitonov, Yad. Fiz. 58 (1995) 651;
Phys. At. Nucl. 58 (1995) 595;
Yad. Fiz. 58 (1995) 1105;
Phys. At. Nucl. 58 (1995) 1031.
J. Van der Jeugt, J. Phys. A 25 (1992) L213; J. Math. Phys. 34 (1993) 1799;
Can. J. Phys. 72 (1994) 519.
G. S. Anagnostatos, Phys. Lett. A 154 (1991) 169.
A. Bulgac and C. Lewenkopf, Phys. Rev. Lett. 71 (1993) 4130.
H. Nishioka, K. Hansen and B. R. Mottelson, Phys. Rev. Β 42 (1990) 9377.
E. Koch, Phys. Rev. A 54 (1996) 670.
V. Ν. Ostrovsky, Phys. Rev. A 56 (1997) 626.